A couple of diamond-related news items have crossed my path lately causing me to consider diamonds and their social implications. I’ll start first with the news items, according to an April 4, 2012 news item on physorg.com a quantum computer has been built inside a diamond (from the news item),

Diamonds are forever – or, at least, the effects of this diamond on quantum computing may be. A team that includes scientists from USC has built a quantum computer in a diamond, the first of its kind to include protection against “decoherence” – noise that prevents the computer from functioning properly.

I last mentioned decoherence in my July 21, 2011 posting about a joint (University of British Columbia, University of California at Santa Barbara and the University of Southern California) project on quantum computing.

According to the April 5, 2012 news item by Robert Perkins for the University of Southern California (USC),

The multinational team included USC professor Daniel Lidar and USC postdoctoral researcher Zhihui Wang, as well as researchers from the Delft University of Technology in the Netherlands, Iowa State University and the University of California, Santa Barbara. The findings were published today in Nature.

The team’s diamond quantum computer system featured two quantum bits, or qubits, made of subatomic particles.

As opposed to traditional computer bits, which can encode distinctly either a one or a zero, qubits can encode a one and a zero at the same time. This property, called superposition, along with the ability of quantum states to “tunnel” through energy barriers, some day will allow quantum computers to perform optimization calculations much faster than traditional computers.

Like all diamonds, the diamond used by the researchers has impurities – things other than carbon. The more impurities in a diamond, the less attractive it is as a piece of jewelry because it makes the crystal appear cloudy.

The team, however, utilized the impurities themselves.

A rogue nitrogen nucleus became the first qubit. In a second flaw sat an electron, which became the second qubit. (Though put more accurately, the “spin” of each of these subatomic particles was used as the qubit.)

Electrons are smaller than nuclei and perform computations much more quickly, but they also fall victim more quickly to decoherence. A qubit based on a nucleus, which is large, is much more stable but slower.

“A nucleus has a long decoherence time – in the milliseconds. You can think of it as very sluggish,” said Lidar, who holds appointments at the USC Viterbi School of Engineering and the USC Dornsife College of Letters, Arts and Sciences.

Though solid-state computing systems have existed before, this was the first to incorporate decoherence protection – using microwave pulses to continually switch the direction of the electron spin rotation.

“It’s a little like time travel,” Lidar said, because switching the direction of rotation time-reverses the inconsistencies in motion as the qubits move back to their original position.

Here’s an image I downloaded from the USC webpage hosting Perkins’s news item,

The diamond in the center measures 1 mm X 1 mm. Photo/Courtesy of Delft University of Technolgy/UC Santa Barbara

I’m not sure what they were trying to illustrate with the image but I thought it would provide an interesting contrast to the video which follows about the world’s first purely diamond ring,

I first came across this ring in Laura Hibberd’s March 22, 2012 piece for Huffington Post. For anyone who feels compelled to find out more about it, here’s the jeweller’s (Shawish) website.

What with the posting about Neal Stephenson and Diamond Age (aka, The Diamond Age Or A Young Lady’s Illustrated Primer; a novel that integrates nanotechnology into a story about the future and ubiquitous diamonds), a quantum computer in a diamond, and this ring, I’ve started to wonder about role diamonds will have in society. Will they be integrated into everyday objects or will they remain objects of desire? My guess is that the diamonds we create by manipulating carbon atoms will be considered everyday items while the ones which have been formed in the bowels of the earth will retain their status.

Nanocellulose seems to be one of the major topics at the ACS’s (Americal Chemical Society) 243rd annual meeting themed Chemistry of Life  in San Diego, California, March 25-29, 2012. From the March 25, 2012 news item on Nanowerk,

… almost two dozen reports in the symposium titled, “Cellulose-Based Biomimetic and Biomedical Materials,” that focused on the use of specially processed cellulose in the design and engineering of materials modeled after biological systems. Cellulose consists of long chains of the sugar glucose linked together into a polymer, a natural plastic–like material. Cellulose gives wood its remarkable strength and is the main component of plant stems, leaves and roots. Traditionally, cellulose’s main commercial uses have been in producing paper and textiles –– cotton being a pure form of cellulose. But development of a highly processed form of cellulose, termed nanocellulose, has expanded those applications and sparked intense scientific research. Nanocellulose consists of the fibrils of nanoscale diameters so small that 50,000 would fit across the width of the period at the end of this sentence.

“We are in the middle of a Golden Age, in which a clearer understanding of the forms and functions of cellulose architectures in biological systems is promoting the evolution of advanced materials,” said Harry Brumer, Ph.D., of Michael Smith Laboratories, University of British Columbia, Vancouver. He was a co-organizer of the symposium with J. Vincent Edwards, Ph.D., a research chemist with the Agricultural Research Service, U.S. Department of Agriculture in New Orleans, Louisiana. “This session on cellulose-based biomimetic and biomedical materials is really very timely due to the sustained and growing interest in the use of cellulose, particularly nanoscale cellulose, in biomaterials.”

One of the presenters has a very charming way of describing the nanocellulose product his team is working on (from the news item),

Olli Ikkala, Ph.D., [Aalto University, Finland] described the new buoyant material, engineered to mimic the water strider’s long, thin feet and made from an “aerogel” composed of the tiny nano-fibrils from the cellulose in plants. Aerogels are so light that some of them are denoted as “solid smoke. [emphasis mine]” The nanocellulose aerogels also have remarkable mechanical properties and are flexible.

There were some 20 presentations in this symposium held under the auspices of the ACS annual meeting. Here’s a few of the presentations (some of these folks have been featured on this blog previously), from the news item,

Native cellulose nanofibers: From biomimetic nanocomposites to functionalized gel spun fibers and functional aerogels Olli Ikkala, Professor, PhD, Aalto University, P.O. Box 5100, Espoo, Finland, FIN-02015, Finland , 358-9-470 23154, olli.ikkala@aalto.fi Native cellulose nanofibers and whiskers attract interest even beyond the traditional cellulose community due to their mechanical properties, availability and sustainability. We describe biomimetic nanocomposites with aligned self-assemblies combining nanocellulose with nanoclays, polymers, block copolymer, or graphene, allowing exciting mechanical properties. Functional ductile and even flexible aerogels are presented, combining superhydrophobicity, superoleophobicity, oil-spill absorption, photocatalytics, optically switchable water absorption, sensing, and antimicrobial properties. Finally mechanically excellent fibers are gel-spun and functionalized for electric, magnetic, optical and drug-release properties.

Evaluation of skin tissue repair materials from bacterial cellulose Lina Fu, Miss, Huazhong University of Science & Technology, College of Life Science & Technology, 1037 Luoyu Road, Wuhan, Hubei, 430074, China , 86-18971560696, runa0325@gmail.com Bacterial cellulose (BC) has been reported as the materials in the tissue engineering fields, such as skin, bone, vascular and cartilage tissue engineering. Exploitation of the skin substitutes and modern wound dressing materials by using BC has attracted much attention. A skin tissue repair materials based on BC have been biosynthesized by Gluconacetobacter xylinus. The nano-composites of BC and chitosan form a cohesive gel structure, and the cell toxicity of the composite is excellent. Unlike other groups, which showed more inflammatory behavior, the inflammatory cells of the BC group were mainly polymorph-nuclear and showed few lymphocytes. The BC skin tissue repair material has an obviously curative effect in promoting the healing of epithelial tissue and reducing inflammation. With its superior mechanical properties, and the excellent biocompatibility, these skin tissue repair materials based on BC have great promise and potential for wound healing and very high clinical value.

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New materials from nanocrystalline cellulose Mark MacLachlan [mentioned in my Nov. 18, 2010 posting], University of British Columbia, Department of Chemistry, 2036 Main Mall, Vancouver, BC, V6T 1Z1, Canada , 604-822-3070, mmaclach@chem.ubc.ca Nanocrystalline cellulose (NCC) is available from the acid-catalyzed degradation of cellulosic materials. NCC is composed of cylindrical crystallites with diameters of ca. 5-10 nm and large aspect ratios. This form of cellulose has intriguing properties, including its ability to form a chiral nematic structure. By using the chiral nematic organization of NCC as a template, we have been able to create highly porous silica films and carbon films with chiral nematic organization.1,2 These materials are iridescent and their structures mimic the shells of jewel beetles. In this paper, I will describe our recent efforts to use NCC to create new materials with interesting optical properties.

Factors influencing chiral nematic pitch and texture of cellulose nanocrystal films Derek G Gray, McGill University, Department of Chemistry, Pulp and Paper Building, 3420 University Street, Montreal, QC, H3A 2A7, Canada , 1-514-398-6182, derek.gray@mcgill.ca Appropriately stabilized cellulose nanocrystal (NCC) suspensions in water form chiral nematic liquid crystalline phases above some critical concentration. In the absence of added electrolye, the chiral nematic pitch of such suspensions is longer than that of visible light. Films prepared by evaporation from the suspensions also often display the characteristic fingerprint patterns characteristic of long-pitch chiral nematic phases, but the pitch values can be shifted into the visible range by adding small quantities of electrolyte to the evaporating suspension. The factors that control the final pitch have been the subject of some confusion. While still not well understood, it is clear that at high nanocrystal concentrations and in solid films, the pitch is not simply a reversible function of nanocrystal concentration. We examine some of the factors that control the pitch and liquid crystal texture during the drying of chiral nematic NCC films.

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Bioprinting of 3D porous nanocellulose scaffolds for tissue engineering and organ regeneration Paul Gatenholm, Professor, [mentioned in my March 19, 2012 posting] Wallenberg Wood Science Center, Chalmers, Department of Chemical and Biological Engineering, Kemigarden 4, Goteborg, V. Gotaland, SE41296, Sweden , 46317723407, paul.gatenholm@chalmers.se Nanocellulose is a promising biocompatible hydrogel like nano-biomaterial with potential uses in tissue engineering and regenerative medicine. Biomaterial scaffolds for tissue engineering require precise control of porosity, pore size, and pore interconnectivity. Control of scaffold architecture is crucial to promote cell migration, cell attachment, cell proliferation and cell differentiation. 3D macroporous nanocellulose scaffolds, produced by unique biofabrication process using porogens incorporated in the cultivation step, have shown ability to attract smooth muscle cells, endothelial cells, chondrocytes of various origins, urethral cells and osteoprogenitor cells. We have developed bioprinter which is able to produce 3D porous nanocellulose scaffolds with large size and unique architecture. Surface modifications have been applied to enhance cell adhesion and cell differentiation. In this study we have focused on use of 3D porous Nanocellulose scaffolds for stem cell differentiation into osteogenic and chondral lineages.